Energy and environmental crisis in the dual pressures, energy conservation and environmentally friendly hybrid cars came into being. Lead carbon battery with low price, HRPSoC mode cycle performance advantages, is the choice of hybrid vehicle power supply. The carbon material mixed in the negative electrode plate of the lead carbon battery can be used as a "buffer", and it is possible to suppress the sulfation of the negative electrode plate. In this paper, the effects of six kinds of graphene materials on the performance of lead-based carbon batteries were discussed. (AGS) and graphene nanosheets (BGS) prepared under different reaction conditions were doped into the negative electrode in different proportions and ways, and their properties were characterized. The results showed that these graphene Materials have a positive impact on battery performance, but the degree of impact is different.